Most of the commands are for administering the running chat, some are only available when you are the chat creator and some more only if you issued before.
Also at some spots in the net it was said, that some commands are only applicable when the "IRC Style" view of chats is activated but I couldn't confirm that.
However, it is also possible to send via SMS, but you will need to add a mobile number and there is a cost for sending the message.
It's not a widespread knowledge that Skype has not only hidden emoticons (see also Skypes own emoticon list)but also allows some special commands within an open Skype chat. There are some lists available on the net but they aren't easy to locate and I found none which has a listing of commands.
I'm seeing a person who a) is a photographer and b) lives in a different country and c) is far more visual than me. I'm now relearning intimacy through a whole new medium. It's not like being right there with someone, but it also doesn't let your imagination run wild like phone sex or sending dirty emails; it's some whole new thing, with its own drawbacks and its own distinct pleasures. Skype sex is like watching porn that stars a person who (hopefully) you know for real, who's aware that you're watching them.
I'm still figuring it all out, but here are a few tips I've learned from my foray into this brave new world of e-humping. It's like porn you direct and co-star in, which is both exciting and nerve-wracking.
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